Heat-curable coating compositions

C - Chemistry – Metallurgy – 09 – D

Patent

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C09D 175/04 (2006.01) C08G 18/08 (2006.01) C08G 18/10 (2006.01) C08G 18/40 (2006.01)

Patent

CA 2029806

The present invention relates to heat-curable coating compositions containing A) a prepolymer having an average of 2-4 ketoxime-blocked NCO groups, having an average molecular weight of 500-15,000 and prepared from aliphatic, cycloaliphatic and aromatic polyisocyanates and one or more polyhydroxy components which contain 0 to 30% by weight of ethylene oxide units and B) a crosslinking agent of the formula (see formula I) wherein R and R1 represent H or C1-C4-alkyl, the ratio of equivalents of blocked NCO groups in A) to NH2 groups in B) being 1.35:1 to 0.95:1, characterized in that at least one of the polyhydroxy compounds used for the preparation of the prepolymer contains, in stable dispersion, a polyurethane, a polyurethane-urea and/or a polyurea, which is substantially free from NCO groups, hydroxyl groups and amino groups and which are synthesized from aromatic, aliphatic and/or cycloaliphatic diisocyanates and from diamines, hydrazine and/or diols, provided that at least one of these components carries a radical having hydrophilic characteristics. The present invention also relates to the use of these coating compositions in a process for the coating, particularly water vapor-permeable coating, of substrates, preferably textile sheet-like structures and leather,

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