Heavy aromatics conversion catalyst composition and...

B - Operations – Transporting – 01 – J

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B01J 29/44 (2006.01) B01J 29/46 (2006.01) B01J 37/08 (2006.01) B01J 38/10 (2006.01) B01J 38/12 (2006.01) C07C 6/12 (2006.01) C07C 7/04 (2006.01) C07C 15/04 (2006.01) C07C 15/08 (2006.01)

Patent

CA 2583223

A catalyst composition, a process for producing the composition and a process for the conversion of a feedstock containing C9+ aromatic hydrocarbons to produce a resulting product containing lighter aromatic products and less than about 0.5 wt % of ethylbenzene based on the weight of C8 aromatics fraction of the resulting product. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene. The catalyst composition comprises (i) an acidity component having an alpha value of at least 300; and (ii) a hydrogenation component having hydrogenation activity of at least 300. The composition can be produced by to incorporating at least one hydrogenation component into an acidity component having an alpha value of at least 300.

La présente invention a pour objet une composition de catalyseur, un procédé permettant d'élaborer cette composition et un procédé de conversion d'une charge contenant des hydrocarbures aromatiques en C9 ou plus. Ledit procédé de conversion permet d'obtenir un produit contenant des composés aromatiques plus légers et moins de 0,5 % en masse environ d'éthylbenzène, par rapport à la masse de la fraction d'aromatiques en C8 dans le produit final. Les hydrocarbures aromatiques en C9 et plus sont convertis dans des conditions de transalkylation en un produit final contenant du xylène. La composition de catalyseur comprend (i) un composant d'acidité dont le coefficient de dissociation (alpha) est d'au moins 300; et (ii) un composant d'hydrogénation dont l'activité hydrogénante est d'au moins 300. La composition peut être produite par incorporation d'au moins un composant d'hydrogénation dans un composant d'acidification de coefficient de dissociation (alpha) au moins égal à 300.

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