C - Chemistry – Metallurgy – 07 – D
Patent
C - Chemistry, Metallurgy
07
D
260/249, 260/251
C07D 409/12 (2006.01) A01N 47/36 (2006.01) C07D 409/04 (2006.01) C07D 409/14 (2006.01) C07D 521/00 (2006.01)
Patent
CA 1259613
Title HERBICIDAL ACETALS AND KETALS Abstract of the Disclosure This invention relates to novel furan- and thiophenesulfonamides such as 3-(1,3-dioxolan-2-yl)-N- [(4-methoxy-6-methyl-1,3-5-triazin-2-yl)aminocarbonyl]- 2-thiophenesulfonamide and N-[(4,6-dimethoxypyrimidin- 2-yl)aminocarbonyl]-3-(1,3-dioxolan-2-yl)-2-thiophene- sulfonamide which are highly active pre-emergent and/or post-emergent herbicides. More specifically, the herbicides are of the formula: Image I wherein Q is Image Q-1 Q-2 Q-3 Image Q-4 Q-5 Q-6 Image , Image , Image or O-7 O-8 O-9 Image O-10 R is H or CH3: R1 is Image , Image or Image E is CH2 or a single bond: R2 is H, C1-C2 alkyl or C1: R3 is H, C1-C3 alkyl or C1-C3 alkoxy: R4 is R5 are independently C1-C2 alkyl: R6 and R7 are independently H or C1-C2 alkyl: W is O or S: W1 is O or S: Q1 and Q2 are independently O, S or NCH3: A is Image , Image , Image A-1 A-2 A-3 Image , Image , Image or A-4 A-5 A-6 Image A-7 X is H, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 halo- alkoxy. C1-C4 haloalkyl . C1-C4 haloalkylthio. C1-C4 alkylthio, halogen, C2-C5 alkoxyalkoxy, amino, C1-C3 alkylamino or di(C1-C3)alkylamino: Y is H. C1-C4 alkyl, C1-C4 alkoxy, C1-C4 halo- alkoxy, C1-C4 haloalkylthio, C1-C4 alkylthio, halogen. C2-C5 alkoxyalkyl, C2-C5 alkoxyalkoxy. amino, C1-C3 alkylamino, di(C1-C3)alkylamino, C3-C4, alkenyloxy, C3-C4 alkynyloxy, C2-C5 alkyl- sulfinylalkyl, C1-C4 haloalkyl, C2-C5 alkyl- sulfonylalkyl. C3-C5 cycloalkyl. C2-C4 alkynyl, C2-C5 alkylthioallsyl. C(O)R8, Image , Image , or N(OCH3)CH3: m is 2 or 3: L1 and L2 are independently O or S: R8 is H or CH3: R9 and R10 are independently C1-C2 alkyl: R11 is C1-C3 alkyl R12 is H. F. C1, NO2. C1-C2 alkyl, C1-2 alkoxy C1-C2 alkylthio, C1-C2 alkylsulfinyl, C1-C2 alkyl- sulfonyl. di(C1-C2)alkylsulfamoyl or CO2(C1-C2 alkyl): R13 is H, C1-C2 alkyl, C1-C2 alkoxy, C1, F or NO2; R14 is H, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 halo- alkyl, C1-C3 haloalkoxy, C1, Br, F, NO2, di(C1-C3)alkylsulfamoyl, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, amino, C1-C3 alkylamino, di(C1-C3)alkylamino, CH2OCH3, CH2SCH3 or CH2CN. Z is CH or N; Y1 is O or CH2; X1 is CH3, OCH3, OC2H5 or OCF2H; and Y2 is H or CH3; X2 is CH3, C2H5 or CH2CF3; Y3 is OCH3, OC2H5, SCH3, SC2H5, OCF2H, SCF2H, CH3 or C2M5; X3 is CH3 or OCH3; Y4 is CH3, OCH3, OC2H5 or C1; and X4 is CH3, OCH3, OC2H5, CH2OCH3 or C1; and their agriculturally suitable salts; provided that a) when X is C1, F, Br, or I, then Z is CH and Y is OCH3, OC2H5, N(OCH3)CH3, NHCH3, N(CH3)2 or OCF2H; b) when Y is cyclopropyl, X is other than C1, F, Br or I; c) when R3 is C1-C3 alkoxy, then Q1 and Q2 are oxygen; d) when R3 is H or C1-C3 alkyl, then Q is Q-1 through Q-9; e) when X or Y is OCF2H, then Z is CH; f) when the total number of carbon atoms of X and Y is greater than four, then the combined number of carbons of the substituents on Q is less than or equal to ten; g) when W is S, then A is A-1, R is H, and Y is CH3, OCH3, OC2H5, CH2OCH3, C2H5, CF3, SCH3, OCH2CH=CH2, OCH2C?CH, OCH2CH2OCH3, CH(OCH3)2 or Image ; h) when A is A-7 and Z is N, then R3 is C1-C3 alkoxy; i) when E is CH2, then R14 is H, CH3, OCH3, C1 or NO2 and is not in the 4-position.
547803
E. I. Du Pont de Nemours And Company
Mccallum Brooks & Co.
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