Heterogeneous anionic polymerization process

C - Chemistry – Metallurgy – 08 – F

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402/457, 402/474

C08F 36/04 (2006.01) B01J 23/04 (2006.01) B01J 27/22 (2006.01) C08F 4/48 (2006.01)

Patent

CA 1083297

ABSTRACT OF THE DISCLOSURE The present invention relates to a heterogeneous anionic polymerization process, catalyzed by a metallic insertion graphitic compound. According to the invention, the alkaline metal chosen for the insertion compound is lithium, and the insertion compounds are of binary or ternary type ; in the latter case, the insertion compound may comprise an aromatic hydrocarbon also inserted within the graphitic structure. The invention relates in particu- lar to the homopolymerization of butadlene or isoprene, and to the copolymerization of isoprene-styrene.

254626

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