Heterogeneous catalyst for preparing alternating...

Details Heterogeneous catalyst for preparing alternating... Heterogeneous catalyst for preparing alternating...

C - Chemistry, Metallurgy

08

G

C08G 67/02 (2006.01)

Patent

CA 2091029

A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by: (a) Pd(O2CNEt2)2(NHEt2)2 supported on a solid carrier preferably constituted by hydroxylated silica, (b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorous atoms capable of linking to Pd atom by dative bonds, (c) NOBF4. Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide (CO).

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