Hexaamminealuminum iodide monoammoniate and process for its...

C - Chemistry – Metallurgy – 01 – F

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C01F 7/00 (2006.01) C30B 25/00 (2006.01) C30B 29/12 (2006.01)

Patent

CA 1295455

HOE 87/H 020 Hexaamminealuminum iodide monoammoniate and process for its preparation Abstract of the Disclosure Cystalline hexaamminealuminum iodide monoammoniate is characterized by certain X-ray diffraction lines (CuK.alpha.) of the 15 strongest lines in order of decreasing intensity. Single crystals of hexaamminealuminum iodide monoammoniate crystallize in the space group Pmn21 with the lattice constants a = 7.600 [.ANG.] b = 13.315 [.ANG.] c = 15.051 [.ANG.] .alpha. = .beta. = .gamma. = 90° and have certain atomic coordinates. Furthermore, processes for the preparation of hexaammine- aluminum iodide monoammoniate by reacting aluminum, an iodine compound and ammonia or aluminum iodide and liquid ammonia are described.

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