High bulk density pvc resin suspension polymerization

C - Chemistry – Metallurgy – 08 – F

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400/4918, 402/54

C08F 2/40 (2006.01) C08F 14/06 (2006.01)

Patent

CA 1285694

ABSTRACT OF THE DISCLOSURE A suspending agent system, a polymerizable reaction mixture, and a polymerization reaction process for producing high bulk density resin on a consistent basis by incorporating in the reaction mixture prior to initiation of the reaction about 1-250 parts per million by weight of polymerization inhibitor and also including about 0.001-.1 parts by weight based on the weight of VCM of a highly hydrolyzed PVA. Preferred PVA's have a 4 weight percent aqueous solution viscosity of 30-100 centipoise and an effective polymerization inhibitor is diethylhydroxylamine. Bulk densities may be increased from about 3-10% depending upon the size of the reaction and the particular ingredients chosen.

543654

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