High productivity process to produce maleic anhydride from...

C - Chemistry – Metallurgy – 07 – D

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C07D 307/60 (2006.01) C07C 51/215 (2006.01) C07C 57/145 (2006.01)

Patent

CA 2301061

In producing maleic anhydride by catalytic oxidation of n-butane in vapor phase using oxygen or enriched air as oxidation medium, the reaction mixture consists of butane, oxygen and a recycling exhaust gas recovered from the absorption stage by a solvent of the maleic anhydride produced in the reaction. In the instant process the carbon monoxide and the carbon dioxide concentration in the reactor mixture are held to on optimum level by performing the reaction on a suitable V.P.O. catalyst, and by feeding to the recycling gases, in addition to butane and oxygen, a carbon dioxide rich gas stream.

Lors de la production d'anhydride maléique par oxydation catalytique de N-butane en phase vapeur en utilisant de l'oxygène ou de l'air enrichi comme milieu oxydant, on obtient un mélange réactif consistant en butane, en oxygène, et en un gaz de recyclage récupéré dans l'étage d'absorption par un solvant de l'anhydride maléique produit dans la réaction. Dans le processus instantané la concentration en CO et en CO¿2? dans le mélange réactif est maintenue à un niveau optimum en conduisant la réaction à l'aide d'un catalyseur VPO adapté et en apportant au gaz de recyclage, en plus du butane et de l'oxygène, un courant gazeux riche en CO¿2?.

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