High rate sputtering of exhaust oxygen sensor electrode

C - Chemistry – Metallurgy – 23 – C

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204/96.08

C23C 14/34 (2006.01) H01J 37/34 (2006.01)

Patent

CA 1240952

HIGH RATE SPUTTERING OF EXHAUST OXYGEN SENSOR ELECTRODE Abstract of the Disclosure: A method of sputtering a platinum exhaust gas electrode onto a vitrified zirconia thimble for an electrochemical-type exhaust gas oxygen sensor. Porous high surface area films are consistently deposited at high rates. A DC magnetron cathode assembly having a magnetic field strength of at least 500 gauss across its target face is used at a sputtering power of about 4 - 9 kilowatts. A thimble-target spacing of less than about 3.0 cm, a pressure less than about 10 millitorr, a sputtering atmosphere consisting essentially of more than about 50 percent nitrogen and/or oxygen, an electrically isolated deposition surface, and an electrically floating reference electrode precoated on the zirconia thimble surface are used.

482058

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