High throughput screen for identifying polymerization...

G - Physics – 01 – N

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G01N 37/00 (2006.01) C08F 4/00 (2006.01) C08F 10/00 (2006.01) C08F 110/14 (2006.01) G01N 30/02 (2006.01) G01N 33/26 (2006.01) C07B 61/00 (2006.01) C08F 4/659 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2379490

A method is disclosed for screening potential catalysts for polymerization performance. The method includes the steps of reacting a potential catalyst with at least a first monomer under polymerization conditions, determining the polymerization performance of the catalyst with the at least first monomer, and using the determination as a predictor for the polymerization performance of the catalyst for at least a second monomer, wherein the first and second monomers are different from each other and the first monomer is an olefin other than ethylene. The method provides a useful, concrete and tangible result that has particular value for identifying appropriate catalysts for olefin polymerization and copolymerization.

La présente invention concerne un procédé permettant vérifier systématiquement le rendement en polymérisation de catalyseurs potentiels. A cet effet, on commence par faire réagit un catalyseur potentiel avec au moins un premier monomère dans des conditions de polymérisation, puis on évalue le rendement en polymérisation du premier monomère considéré. On utilisera alors cette évaluation comme base de prédiction pour le rendement en polymérisation du catalyseur pour au moins un deuxième monomère. En l'occurrence, ces deux monomères sont différents l'un de l'autre, le premier monomère étant une oléfine autre que l'éthylène. Ce procédé donne des résultats utiles, concrets et tangibles présentant une valeur particulière pour l'identification de catalyseurs convenant à la polymérisation et la copolymérisation oléfinique.

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