Hollow inorganic membranes produced by metal or composite...

C - Chemistry – Metallurgy – 25 – D

Patent

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Details

C25D 13/02 (2006.01) C04B 38/06 (2006.01) C04B 41/50 (2006.01) C25D 1/14 (2006.01) C25D 13/14 (2006.01) H01M 8/12 (2006.01)

Patent

CA 2472778

This invention relates to a method of producing a hollow inorganic membrane that is particularly suitable for solid oxide fuel cell applications, as well as producing hollow inorganic composite laminated membranes having at least one such hollow inorganic membrane. The method comprises electrodepositing an inorganic material that includes at least some electrically conductive metal and some ionically conductive ceramic onto an electrically conductive combustible core, drying the core bearing the deposited inorganic material, then, sintering the core bearing the deposited inorganic material such that the core combusts, thereby producing a hollow inorganic membrane. The method may further comprises electrophoretically depositing a ceramic composition onto the hollow inorganic membrane, to produce an assembly of hollow inorganic composite laminated membranes.

L'invention concerne un procédé de production membranes inorganiques creuses qui conviennent particulièrement pour des applications de piles à combustible à oxyde solide, ainsi que de production de membranes stratifiées composites inorganiques creuses possédant au moins une telle membrane inorganique creuse. Le procédé consiste à déposer par électrodéposition un matériau inorganique renfermant au moins un métal électroconducteur et un matériau céramique à conduction ionique sur un noyau combustible électroconducteur, à sécher le noyau portant le matériau inorganique déposé, puis à fritter ledit noyau portant le matériau inorganique déposé de façon que le noyau brûle, produisant ainsi une membrane inorganique creuse. Le procédé peut en outre consister à déposer par électrophorèse une composition céramique sur la membrane inorganique creuse pour produire un ensemble de membranes stratifiées composites inorganiques creuses.

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