Hybrid, organic-inorganic, crystalline, porous silicates and...

C - Chemistry – Metallurgy – 01 – B

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C01B 37/00 (2006.01)

Patent

CA 2754292

The present invention relates to new hybrid, organic-inorganic hybrid silicates and metal-silicates characterized by a crystalline structure containing structural units having formula (a), wherein R is an organic group possibly containing one or more element T selected from Group IIIB, IVB, VB and from transition metals. A process starting from cyclic trisilanes for the preparation of said materials, is also described. These materials can be used as molecular sieves, adsorbents, in the field of catalysis, in the field of electronics, in the field of sensors, in the area of nanotechnology.

La présente invention porte sur de nouveaux silicates et silicates métalliques hybrides, organiques-inorganiques hybrides caractérisés par une structure cristalline contenant des unités structurales ayant la formule (a), dans laquelle R est un groupe organique contenant possiblement un ou plusieurs éléments T choisis dans le Groupe III, IVB, VB et parmi les métaux de transition. L'invention porte également sur un procédé démarrant à partir de trisilanes cycliques pour la préparation desdits matériaux. Ces matériaux peuvent être utilisés en tant que tamis moléculaires, adsorbants, dans le domaine de la catalyse, dans le domaine de l'électronique, dans le domaine des capteurs, dans le domaine des nanotechnologies.

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