C - Chemistry – Metallurgy – 10 – G
Patent
C - Chemistry, Metallurgy
10
G
196/133, 196/136
C10G 45/00 (2006.01) B01J 23/85 (2006.01) B01J 35/10 (2006.01) C10G 45/04 (2006.01) C10G 65/04 (2006.01)
Patent
CA 1038789
A B S T R A C T A process for the catalytic hydrodesulphurization without catalyst replenishment of vanadium- and nickel-containing residual hydrocarbon oils, which process is carried out in the presence of an amount of water corresponding to a water-vapour partial pressure in the process of 0.5-30 bar and in the presence of a catalyst which has a total pore volume above 0.30 ml/g, less than 10% of the total pore volume being present in pores with a diameter above 100 nm, and such a specific average pore diameter (p) and specific average particle diameter (d) that the quotinet p/(d)0.9 meets the requirement 4 x 10-4x(pH2)2 ? p/(d)0.9 ? 5 + 24 x 10-4 x (pH2)2, in which pH2 is the hydrogen partial pressure applied (p in nm, d in nm, pH2 in bar).
210553
Oelderik Jan M.
Pronk Karel M.a.
Sie Swan T.
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