Hydrocarbon oxidations catalyzed by azide-activated metal...

Details Hydrocarbon oxidations catalyzed by azide-activated metal... Hydrocarbon oxidations catalyzed by azide-activated metal...

C - Chemistry, Metallurgy

07

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260/586, 260/196

C07F 11/00 (2006.01) B01J 27/24 (2006.01) B01J 31/18 (2006.01) C07C 27/12 (2006.01) C07C 29/50 (2006.01) C07C 45/33 (2006.01) C07C 45/34 (2006.01) C07C 45/35 (2006.01) C07C 45/36 (2006.01) C07C 49/08 (2006.01) C07C 49/403 (2006.01) C07F 13/00 (2006.01)

Patent

CA 1336188

Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O2 to form such products as alcohols, ketones, and the like selectively in high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure Image , where M is a transition metal; " Image " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.

553420

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