C - Chemistry – Metallurgy – 10 – G
Patent
C - Chemistry, Metallurgy
10
G
C10G 69/08 (2006.01)
Patent
CA 2113810
Low sulfur gasoline of relatively high octane number is produced from, a catalytically cracked, sulfur-containing naphtha by hydrodesulfurisation followed by treatment over an acidic catalyst, preferably an intermediate pore size zeolite such as ZSM-5. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment arid results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha. A catalytically cracked naphtha from the FCC main column (10) is first hydrotreated in a hydrotreater (11) which it enters through inlet (12). From hydrotreater (11), the desulfurised naphtha passes through line (13) to the second reactor (14) in which it is contacted with ZSM-5 or another acidic catalyst, for example zeolite beta or MCM-22 where a controlled degree of cracking takes place with an octane, which was lost in the hydrotreater, being restored. The effluents from reactor (14) are separated and further processed.
Angevine Philip J.
Apelian Minas R.
Collins Nick A.
Degnan Thomas F. Jr.
Diez Douglas S.
Kirby Eades Gale Baker
Mobil Oil Corporation
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