Hydrocarbonylation of methanol to ethanol in the presence of...

Details Hydrocarbonylation of methanol to ethanol in the presence of... Hydrocarbonylation of methanol to ethanol in the presence of...

C - Chemistry, Metallurgy

07

C

260/639

C07C 31/08 (2006.01) C07C 29/32 (2006.01) C07C 51/12 (2006.01)

Patent

CA 1105060

ABSTRACT Ethanol is produced by contacting a fixture of methanol and synthesis gas at elevated temperature and pressure with a cobalt-containing catalyst in the presence of added acids and/or acid derivatives, e,g, acetic acid and methyl acetate. Optionally a catalyst promoter such as iodine, bromine or an organo-phosphorus compound is also added. Optionally also non-polar solvents such as alkanes, benzene and alkyl substituted benzenes may be added.

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