Hydrocarboxylation of unsaturated carboxylic acids to linear...

Details Hydrocarboxylation of unsaturated carboxylic acids to linear... Hydrocarboxylation of unsaturated carboxylic acids to linear...

C - Chemistry, Metallurgy

07

C

260/524.1

C07C 51/14 (2006.01) C07C 55/02 (2006.01)

Patent

CA 1248137

TITLE HYDROCARBOXYLATION OF UNSATURATED CARBOXYLIC ACIDS TO LINEAR DICARBOXYLIC ACIDS ABSTRACT OF THE DISCLOSURE The preparation of linear dicarboxylic acids, e.g., adipic acid by hydrocarboxylating unsaturated monocarboxylic acids, e.g., 3-pentenoic acid with carbon monoxide and water in the presence of a rhodium-containing catalyst, an iodide promoter and certain inert halocarbon solvents , e.g., methylene chloride.

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