Hydrodearomatization of hydrocarbon oils using novel...

B - Operations – Transporting – 01 – J

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B01J 27/049 (2006.01) B01J 23/85 (2006.01) B01J 27/051 (2006.01) B01J 27/14 (2006.01) B01J 27/188 (2006.01) C10G 45/08 (2006.01) C10G 45/44 (2006.01) C10G 45/50 (2006.01) C10G 47/06 (2006.01)

Patent

CA 2155086

A process for simultaneous hydrodearomatization, hydrodesulfurization and hydrodenitrogenation of a charge hydrocarbon oil containing undesired aromatic components, sulfur and nitrogen compounds, which comprises: maintaining a bed of a sulfided metal catalyst comprising one or more metals of non-noble Group VIII, at least one metal selected from tungsten and molybdenum on a novel "phosphorus treated carbon" support, the "phosphorus treated carbon" support being comprised of phosphorus bound to the carbon surface predominantly as polyphosphate species characterized by peaks between -5 and -30 ppm in the solid-state magic angle spinning 31p nuclear magnetic resonance spectrum; passing a charge hydrocarbon feed in the presence of hydrogen into contact with said catalyst at hydrotreating conditions, thereby effecting hydrodearomatization, and simultaneously effecting hydrodesulfurization and hydrodenitrogenation.

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