Hydrodynamic recycle of metallic sulfide seed under pressure

C - Chemistry – Metallurgy – 22 – B

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53/310, 53/379

C22B 7/00 (2006.01) B01J 3/04 (2006.01) C01G 1/12 (2006.01) C01G 53/11 (2006.01) C22B 3/44 (2006.01)

Patent

CA 1214335

ABSTRACT OF THE DISCLOSURE A process is provided for continuously precipi- tating precipitate-forming ions under elevated temperature and pressure from a solution thereof using recycle precipi- tate seed as a precipitation aid. The process comprises establishing a solution of the precipitation-forming ions, feeding the solution at an elevated temperature and pressure through an autoclave having a series of precipi- tation compartments, and adding a precipitation agent to the solution while it is maintained under elevated tempera- ture and pressure to precipitate the precipitation-forming ions and thus form a precipitate slurry. The slurry is caused to flow out of the autoclave by virtue of the prevailing pressure in the system to a solids-liquid separator which is serially connected in pressure communi- cation with the autoclave, the separator having a dense slurry fluidized leg or an elutriation column and being disposed at an elevation relative to the autoclave to pro- vide a hydrostatic head of the withdrawn slurry in gravity- flow relationship to the autoclave. The precipitate may be continuously elutriated in the column under the pre- vailing pressure so as to provide an upper slurry portion of precipitate fines and a lower portion of product con- centrate. The precipitate fines are then caused to flow by gravity as seed material to the autoclave without requiring the use of pumps for circulating the slurry.

430187

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