Hydroformylation of olefin feeds containing dienes

Details Hydroformylation of olefin feeds containing dienes Hydroformylation of olefin feeds containing dienes

C - Chemistry, Metallurgy

07

C

C07C 45/49 (2006.01) C07C 29/16 (2006.01)

Patent

CA 2265318

A process for the hydroformylation of a feed comprising compounds having a single ethylenically unsaturated group by reaction thereof in the liquid phase with carbon monoxide and hydrogen in the presence of a catalyst system comprising a) a source of palladium cations; b) a source of anions; c) a source of at least one bidentate ligands of the formula R1R2M1RM2R3R4 (I) wherein M1 and M2 independently represent a phosphorus, arsenic or antimony atom, R represents a bivalent bridging group containing from 1-4 atoms in the bridge, R1 and R2 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M1, and R3 and R4 independently represent a substituted or unsubstituted hydrocarbyl group, or together represent a bivalent substituted or unsubstituted cyclic group whereby the two free valencies are linked to M2; and d) a source of halide chosen from the group of chloride, iodide and bromide and mixtures thereof; characterized in that the ethylenically unsaturated feed comprises one or more dienes and/or further multiply unsaturated alkenes to an amount of 0.005 - 5 wt% based on the total amount of ethylenically unsaturated compounds in the feed, and in that component b) of the catalyst system comprises a source of anions of an acid having a pKa value, measured in aqueous solution at 18 °C, of between -1 and 4.

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