Hydroformylation of olefins

C - Chemistry – Metallurgy – 07 – C

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260/573.2, 260/6

C07C 27/20 (2006.01) B01J 31/22 (2006.01) C07C 45/50 (2006.01)

Patent

CA 1057307

HYDROFORMYLATION OF OLEFINS ABSTRACT OF THE DISCLOSURE Olefins are converted to aldehydes and/or alcohols having one more carbon atom than the olefin by reacting the olefin with carbon monoxide and hydrogen in the presence of an in situ formed catalytic complex of a Group VIII metal, carbon monoxide and a trivalent ligand, the metal being introduced into the reaction zone in the form of a solution of a water-soluble inorganic salt dissolved in a solvent comprised of at least 40% by volume of a polyalkylene glycol, the polyalkylene glycol acting as a coupling agent preventing precipitation of the metal prior to formation of the catalyst complex.

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