Hydroformylation using low volatile phosphine ligands

C - Chemistry – Metallurgy – 07 – C

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260/573.2

C07C 45/50 (2006.01) C07C 47/02 (2006.01)

Patent

CA 1307296

HYDROFORMYLATION USING LOW VOLATILE PHOSPHINE LIGANDS ABSTRACT An improved non-aqueous hydroformylation process for producing aldehydes which comprises reacting an olefinically unsaturated organic compound with carbon monoxide and hydrogen, in a non-aqueous hydroformylation reaction medium containing the olefinically unsaturated organic compound, aldehyde product, solubilized Group VIII transition metal-phosphorus ligand complex catalyst and solubilized free phosphorus ligand, the improvement comprising employing as the phosphorus ligand of said complex catalyst and as said free phosphorus ligand, a monosulfonated tertiary phosphine metal salt and wherein said hydroformylation reaction medium also contains at lest a sufficient amount of an added organic solubilizing agent capable of rendering the Group VIII transition metal-monosulfonated tertiary phosphine metal salt ligand complex catalyst and free monosulfonated tertiary phosphine metal salt ligand employed, soluble in said hydroformylation reaction medium. D-15446

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