Hydrogels of absorbable polyoxaesters

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

C08G 63/66 (2006.01) A61K 47/34 (2006.01) A61L 17/00 (2006.01) A61L 31/00 (2006.01) C08G 63/664 (2006.01) C08G 63/672 (2006.01) C08G 63/91 (2006.01) C08L 67/00 (2006.01) C09D 167/00 (2006.01)

Patent

CA 2220351

The present invention describes a new crossslinkable and crosslinked aliphatic polyoxaesters and blends thereof that may be used to produce hydrogels, surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The invention also contemplates a process for producing these polyesters. The crosslinked aliphatic polyoxaesters of the present invention are formed from an aliphatic polyoxaesters a first divalent repeating unit of formula I: [O-C(O)-C(R1)(R2)-O-(R3)-O-C(R1)(R2)-C(O)-] I and a second repeating unit selected from the group of formulas consisting of: [-O-R4-]A, II [-O-R5-C(O)-]B, and III ([-O-R5-C(O)]p-O-)LG XI and combination thereof. These aliphatic polyoxaesters may be blended with other polymers which are preferably biocompatable.

La présente invention concerne de nouveaux polyoxaesters aliphatiques réticulables et réticulés et des mélanges de ces derniers qui peuvent être utilisés pour produire des hydrogels, des dispositifs chirurgicaux comme les fils à suturer, des ensembles fil-aiguille, des dispositifs moulés et d'autres produits semblables. L'invention porte également sur un procédé pour produire ces polyesters. Les polyoxaesters aliphatiques réticulés de la présente invention sont formés à partir de polyoxaesters aliphatiques ayant un premier motif divalent de formule I : [O-C(O)-C(R1)(R2)-O-(R3)-O-C(R1)(R2)-C(O)-] I et un second motif choisi parmi le groupe de formules constitué de : [-O-R4-]A, II [-O-R5-C(O)-]B, III et ([-O-R5-C(O)]p-O-)LG XI et des combinaisons de ces derniers. Ces polyoxaesters aliphatiques peuvent être mélangés avec d'autres polymères qui sont préférablement biocompatibles.

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