Hydrogen peroxide hydroxylation process in a super acid...

C - Chemistry – Metallurgy – 07 – C

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260/474, 260/557

C07C 69/035 (2006.01) C07C 69/96 (2006.01) C07C 233/02 (2006.01)

Patent

CA 1197521

PRECIS DE LA DIVULGATION: L'invention concerne un procédé d'hydroxylation de dérivés du phénol et de l'aniline par le peroxyde d'hy- drogène, donnant une proportion importante de dérivé mono- hydroxylé en méta, caractérisé en ce que l'on fait réagir le peroxyde d'hydrogène dans un milieu superacide liquide, à des températures allant d'environ -80°C à 0°C, sur des com- posés répondant à la formule générale: Image dans laquelle X représente un atome d'oxygène ou un radical - NH -, et R représente un atome d'hydrogène, un radical alkyle, cycloalkyle ou aryle, ou un radical alcoxy, cyclo- alcoxy ou aryloxy.

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