Hydrogen production

C - Chemistry – Metallurgy – 01 – B

Patent

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Details

23/314, 204/78.3

C01B 3/00 (2006.01) C01B 3/04 (2006.01) C25B 1/02 (2006.01)

Patent

CA 1089632

ABSTRACT The production of hydrogen by reacting a carbonaceous material with water and at least one halogen selected from the group consisting of chlorine, bromine and iodine to form reaction products including carbon dioxide and a corresponding hydrogen halide. The hydrogen halide is decomposed to separately release the hydrogen and the halogen. The halogen is recovered for reaction with additional carbonaceous materials and water, and the hydrogen is recovered as a salable product. In a preferred embodiment the carbonaceous material, water and halogen are reacted at an elevated temperature. In accordance with another embodiment, a continuous method for the production of hydrogen is provided wherein the carbonaceous material, water and at least one selected halogen are reacted in one zone, and the hydrogen halide produced from the reaction is decomposed in a second zone, preferably by electrolytic decomposition, to release the hydrogen for recovery and the halogen for recycle to the first zone.

282706

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