Hydrogenation of aromatic amines to alicyclic amines using a...

C - Chemistry – Metallurgy – 07 – C

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C07C 209/72 (2006.01) B01J 21/02 (2006.01) B01J 23/04 (2006.01) B01J 23/46 (2006.01) C07C 211/35 (2006.01)

Patent

CA 2559787

The present invention relates to processes for the catalytic hydrogenation of aromatic amines to their acyclic counterparts using a ruthenium catalyst on a lithium aluminate support. The hydrogenation process comprises contacting an aromatic amine with hydrogen in the presence of a ruthenium catalyst under temperature and pressure conditions suitable to effect ring hydrogenation. The process is especially useful for hydrogenating aniline to cyclohexylamine.

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