Hydroxyl-protecting groups orthogonally removable by...

Details Hydroxyl-protecting groups orthogonally removable by... Hydroxyl-protecting groups orthogonally removable by...

C - Chemistry, Metallurgy

07

H

C07H 21/00 (2006.01) C07H 19/06 (2006.01) C07H 19/10 (2006.01)

Patent

CA 2088255

2088255 9202533 PCTABS00010 Hydroxyl-protecting groups orthogonally removable by reduction with a liquid reducing agent are disclosed. The novel hydroxyl-protecting groups are particularly useful in the chemical synthesis of linear and branched oligonucleotide structures, as they are readily removed from the protected molecule with mild reagents such as dithionite. Examples of such hydroxyl-protecting groups include the 2-methylene-9,10-anthraquinone (Maq) carbonate ester and the p-nitrobenzyl carbonate ester.

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