Ignition improved fuels

C - Chemistry – Metallurgy – 10 – L

Patent

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Details

C10L 1/18 (2006.01) C10L 1/14 (2006.01) C10L 1/22 (2006.01) C10L 1/224 (2006.01) C10L 10/00 (2006.01) C10L 10/02 (2006.01) C10L 1/16 (2006.01)

Patent

CA 2315683

A fuel is presented which is doped with 0.01-10 % by weight of cyclic ketone peroxide(s), characterized in that it comprises from 0.01 to 10 percent by weight of cyclic ketone peroxides of formula (I) wherein R1-R6 are independently selected from the group consisting of hydrogen, C1-C20 alkyl, C3- C20 cycloalkyl, C6-C20 aryl, C7-C20 aralkyl, and C7-C20 alkaryl, which groups may include linear or branched alkyl moieties; and each of R1-R6 may optionally be substituted with one or more groups selected from hydroxy, alkoxy, linear or branched alkyl, aryloxy, ester, carboxy, nitrile, and amido, with the proviso that said peroxides make up at least 35 % by weight of all peroxides in the fuel, to reduce the emission of pollutants when the fuel is used in a combustion engine. Also the process to make such fuels is presented.

Cette invention concerne un carburant dopé avec 0,01-10 % en poids de peroxyde(s) de cétone cyclique, caractérisé en ce qu'il renferme entre 0,01 à 10 % en poids de peroxydes de cétone cyclique de formule (I) où: R¿1?-R¿6? sont indépendamment choisis dans le groupe comprenant hydrogène, alkyle C¿1?-C¿20?, cycloalkyle C¿3?-C¿20?, aryle C¿6?-C¿20?, aralkyle C¿7?-C¿20? et alkaryle C¿7?-C¿20?, lesquels groupes peuvent renfermer des fractions alkyle linéaires ou ramifiées, chacun des groupes R¿1?-R¿6? pouvant être éventuellement substitués par un ou plusieurs groupes choisis parmi hydroxy, alcoxy, alkyle linéaire ou ramifié, aryloxy, ester, carboxy, nitrile et amido, à condition que lesdits peroxydes représentent au moins 35 % en poids de tous les peroxydes présents dans le carburant, le but étant de réduire les émissions polluantes lorsque ledit carburant est utilisé dans un moteur thermique. L'invention concerne également un procédé de fabrication de tels carburants.

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