Implementation of a strategy for achieving extraordinary...

C - Chemistry – Metallurgy – 07 – F

Patent

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C07F 3/00 (2006.01)

Patent

CA 2524903

The present invention provides a metal-organic framework ("MOF~) comprising a plurality of metal clusters and a plurality of multidentate, linking ligands. Each metal of the plurality of metal clusters comprises one or more metal ions. Each ligand of the plurality of multidentate linking ligands connects adjacent metal clusters. The present invention also provides a method of forming the metalorganic framework. The method of the invention comprises combining a solution comprising one or metal ions with a multidentate linking ligand having a sufficient number of accessible sites for atomic or molecular adsorption that the surface area of the resulting metal-organic framework is greater than 2,900 M2/g.

La présente invention concerne une structure organométallique comprenant une pluralité de grappes de métaux et une pluralité de coordinats multicoordinants de liaison. Chaque métal de la pluralité de grappes de métaux comprend un ou plusieurs ions de métal. Chaque coordinat de la pluralité de coordinats multicoordinants de liaison relie des grappes de métaux adjacentes. L'invention concerne également un procédé de formation de la structure organométallique. Pour ce procédé, on prend une solution comprenant un ou plusieurs ions de métal et on la combine avec un coordinat multicoordinant de liaison disposant d'un nombre suffisant de sites accessibles pour une adsorption atomique ou moléculaire faisant que la superficie de la structure organométallique résultante soit supérieure à 2.900 m?2¿/g.

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