Improved catalyst and process for the synthesis of butene-1...

C - Chemistry – Metallurgy – 07 – C

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252/109, 260/706

C07C 11/08 (2006.01) B01J 31/14 (2006.01) C07C 2/30 (2006.01)

Patent

CA 1234383

PRECIS DE LA DIVULGATION: L'invention concerne un catalyseur, utilisable pour la conversion de l'éthylène en butène-1,caractérisé en ce qu'il résulte de l'interaction d'un mélange préformé de titanate d'alkyle et d'éther dans un rapport molaire éther/titanate de 0,5 : 1 à 10 : 1 avec un composé d'aluminium de formule AlR3 ou AlR2H dans laquelle chacun des restes R est un radical hydrocarbyle. L'invention concerne également un procédé amélioré de conversion de l'éthylène en butène-1, dans lequel on met l'éthylène en contact avec un catalyseur selon l'invention.

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