Improved catalytic composition and procedure for the...

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B01J 31/14 (2006.01) B01J 31/04 (2006.01) B01J 31/12 (2006.01) C07C 2/24 (2006.01) C07C 2/30 (2006.01) C08F 4/42 (2006.01)

Patent

CA 2414399

A catalytic composition for oligomerizing ethylene, in particular to 1-hexene, is obtained by mixing at least one chromium carboxylate characterized in that it also contains a free carboxylic acid in a set proportion, with at least one aryloxy compound of an element M selected from the group formed by magnesium, calcium, strontium and barium, with general formula M(RO)2-nXn in which RO is an aryloxy radical containing 6 to 80 carbon atoms, X is a halogen atom or a hydrocarbyl radical containing 1 to 30 carbon atoms and n is a whole number that can take the values 0 or 1, and with at least one hydrocarbylaluminum compound selected from the group formed by tris(hydrocarbyl)-aluminum compounds, chlorinated or brominated hydrocarbylaluminum compounds and aluminoxanes.

Une composition catalytique pour l'oligomérisation de l'éthylène, en particulier en hexène-1, est obtenue par mélange d'au moins un carboxylate de chrome caractérisé en ce qu'il contient en outre de l'acide carboxylique libre en proportion définie, avec au moins un composé aryloxy d'un élément M choisi dans le groupe formé par le magnésium, le calcium, le strontïum, le baryum, de formule générale M(RO)2nXn dans laquelle RO est un radical aryloxy contenant de 6 à 80 atomes de carbone, X est un atome d'halogène ou un radical hydrocarbyle contenant de 1 à 30 atomes de carbone et n est un nombre entier qui peut prendre les valeurs 0 et 1, et avec au moins un composé d'aluminium hydrocarbyle choisi dans le groupe formé par les composés tris(hydrocarbyl)-aluminium, les composés chlorés ou bromés d'hydrocarbylaluminium et les aluminoxanes.

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