Improved initiator systems for curing unsaturated polyester...

C - Chemistry – Metallurgy – 08 – F

Patent

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C08F 4/32 (2006.01) C08F 263/00 (2006.01) C08F 283/01 (2006.01) C08K 5/14 (2006.01) C08L 31/02 (2006.01) C08L 67/06 (2006.01)

Patent

CA 2207365

Disclosed are heat-curable polymer compositions comprising a resin of ethylenically unsaturated polyester or vinyl ester, an organic peroxide initiator component, a promoter for decomposition of said peroxide, and an inhibitor of polymerization of the resin, wherein the inhibitor is present in an amount with respect to the amount of promoter present such that the gel time of the composition is independent of the amount of promoter present. Observance of the indicated ratio between promoter and inhibitor provides the advantages of both components and also enables the operator to obtain curing performance and characteristics as a function solely of the peroxide content of the composition.

On présente des compositions de polymères thermo-durcissables comprenant une résine de polyester ou d'ester vinylique insaturée, un élément organique initiateur de peroxide, un accélérateur pour la décomposition de ce peroxide et un inhibiteur pour la polymérisation de la résine. Cet inhibiteur est présent en quantité relative à la quantité d'accélérateur pour que la période de gel de la composition ne soit pas dépendante de la quantité présente d'accélérateur. Le respect des proportions indiquées entre l'accélérateur et l'inhibiteur offre les avantages des deux éléments en permettant aussi à l'opérateur d'obtenir le rendement et les caractéristiques de polymérisation comme fonction unique du contenu en peroxide de la composition.

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