Improved olefin metathesis process

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

260/692, 260/708

C07C 6/04 (2006.01) B01J 31/34 (2006.01) C07C 11/02 (2006.01)

Patent

CA 1094108

ABSTRACT OF THE DISCLOSURE An improved process for metathesizing olefins is provided which involves contacting the olefin at a temperature of 50 - 220°C under substantially anhydrous conditions with a particular homogeneous catalyst. The catalyst is obtained by the use of a trivalent phosphorous modifying agent with a cocatylst comprised of tungsten hexachloride and a organotin compound. This process gives significantly increased conversions and excellent product selectivity. These improved results are obtained without regard to the source and storage history of the tungsten compound.

291263

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