Improved phosphorous/vanadium oxidation catalyst

B - Operations – Transporting – 01 – J

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B01J 23/06 (2006.01) B01J 23/22 (2006.01) B01J 23/28 (2006.01) B01J 27/199 (2006.01) C07C 51/215 (2006.01) C07D 307/60 (2006.01)

Patent

CA 2042548

An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus, zinc and lithium mixed oxides which comprises adding a molybdenum compound modifier in an amount of from about 0.005 to 0.025/1 Mo/V to the catalyst during the digestion of the reduced vanadium compound by concentrated phosphoric acid. The addition of Mo produces a catalyst which is very stable more active system and longer lived than the unmodified catalyst.

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