In situ comonomer generation in olefin polymerization

C - Chemistry – Metallurgy – 08 – F

Patent

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252/100, 402/631

C08F 10/00 (2006.01) C08F 4/69 (2006.01) C08F 10/02 (2006.01) C08F 110/02 (2006.01)

Patent

CA 1292734

Abstract of the Disclosure The catalyst system is produced by first forming a chromium catalyst on a predominantly silica support, activating in an oxygen- containing ambient and thereafter subjecting the thus activated composition to carbon monoxide reduction. The resulting reduced supported chromium catalyst composition is then precontacted with a cocatalyst selected from trialkyl boron compounds and dialkyl aluminum alkoxide compounds, preferably triethyl borane and thereafter contacted with ethylene. This results in a catalyst system which produces comonomer in situ so as to give tough, flexible ethylene copolymers from an essentially pure ethylene feed.

531796

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