Incorporation of pigment derivatives in quinacridone processes

C - Chemistry – Metallurgy – 09 – B

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C09B 48/00 (2006.01) C09B 57/00 (2006.01) C09B 67/22 (2006.01)

Patent

CA 2199597

This invention relates to a process for the preparation of quinacridone pigments by (a) ~heating, at a temperature of about 80°C to about 145°C, a reaction mixture containing (i) ~2,5-dianilinoterephthalic acid, a 2,5-dianilino-3,6-dihydro- terephthalic acid ester, and/or a derivative thereof, (ii) ~about 3 to about 15 parts by weight, per part of component (a)(i), of a dehydrating agent, and (iii) ~about 0.1 to about 15 percent by weight, based ~on component (a)(i), of one or more non-quinacridone pigments, with the proviso that if component (a)(i) is a 2,5-dianilino-3,6- dihydroterephthalic acid ester or a derivative thereof, reaction step (a) additionally comprises an oxidation step; (b) ~drowning the reaction mixture from step (a) by adding said reaction mixture to about 3 to about 15 parts by weight, per part of component (a)(i), of a liquid in which the quinacridone pigment is substantially insoluble; (c) ~isolating the quinacridone pigment; (d) ~optionally, conditioning the quinacridone pigment; and (e) ~optionally, blending the resultant pigment with one or more quinacridone derivatives.

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