Inhibiting scale in vinyl monomer polymerization

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 14/08 (2006.01) C08F 2/01 (2006.01) C08F 2/44 (2006.01) C08F 14/06 (2006.01) C08L 27/06 (2006.01) C08L 61/34 (2006.01) C23F 14/02 (2006.01)

Patent

CA 2339975

Disclosed is a method of inhibiting the formation of scale on reactor surfaces in contact with a polymerizing vinyl monomer comprising contacting said monomer with a terpolymer which comprises the condensation reaction product of (A) an aromatic compound that contains the group (I) or (II) where Q is OR or SR and R is hydrogen, alkyl from C1, to C15, or aryl, alkaryl, or aralkyl from C6 to C15 (B) about 0.1 to about 10 moles of a carbonyl compound per mole of said aromatic compound; and (C) about 0.1 to about 10 moles of a thiourea per mole of said aromatic compound.

L'invention concerne un procédé inhibant la formation de dépôts sur les surfaces d'un réacteur au contact d'un monomère vinylique en polymérisation, consistant à mettre en contact ledit monomère avec un terpolymère comprenant le produit de réaction de condensation de (A) un composé aromatique contenant les groupes (I) ou (II) dans lesquels Q représente OR ou SR et R représentent hydrogène, alkyle C¿1? à C¿15? ou aryle, alkyle ou aralkyle C¿6? à C¿15?, (B) environ 0,1 à environ 10 moles d'un composé de carbonyle par mole dudit composé aromatique; et (C) environ 0,1 à environ 10 moles d'une thiourée par mole dudit composé aromatique.

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