Initiator systems for polymerisable compositions

C - Chemistry – Metallurgy – 08 – F

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C08F 4/58 (2006.01) C07F 7/21 (2006.01)

Patent

CA 2542830

The present invention relates to complexes of organoboranes with amino functional organosilicon compounds which are effective polymerisation initiators for radically polymerisable systems, especially acrylate or methacrylate adhesives. The complexes are partcularly useful in the preparation of adhesives for bonding low surface energy plastics based on, for example, polyolefins and polyfluoroolefins.

L'invention concerne des complexes d'organoboranes comprenant des composés organosiliciés à fonction amino, qui sont des amorceurs de polymérisation efficaces pour des systèmes radicalement polymérisables, en particulier des adhésifs d'acrylate et de méthacrylate. Les complexes de l'invention sont particulièrement utiles dans la préparation d'adhésifs basés, par exemple, sur des polyoléfines et des polyoléfines fluorées, destinés à coller des plastiques à faible énergie de surface.

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