Insecticidal dihydro-oxadiazines, -thiadiazines and -triazines

C - Chemistry – Metallurgy – 07 – D

Patent

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Details

C07D 273/04 (2006.01) A01N 47/38 (2006.01) A01P 7/04 (2006.01) C07D 413/04 (2006.01)

Patent

CA 2318889

Insecticidal dihydro-oxadiazine compounds having formula (I): wherein X is O, N or S; R is a substituted or unsubstituted phenyl or C4-C5 heterocyclic group; R2, R3, R4, and R5 are one of the following: a) R2, R3, and R4 are independently, hydrogen, alkyl, alkoxy, or furanyl; and R5 is nitro, cyano, alkyl, dialkylamino, alkylthio, alkoxy, haloalkoxy, phenoxy, phenylthio, or alkoxycarbonyl, wherein R3 and R5 together can form a ring; or b) R3, R4, and R5 are hydrogen; and R2 is alkylthio, alkylsulfinyl, alkylsulfonyl, nitroalkoxy, hydroxy, dialkoxyphosphinyl, cyano, acyloxy, alkoxy, haloalkoxy, cycloalkyl, or alkenyl; or R2 is a substituted or unsubstituted phenyl, phenylthio, phenylsulfinyl, phenylsulfonyl, pyrazolyl, furanyl, thienyl, phenylalkoxy, or benzoyloxy; and R6 is hydrogen alkyl, alkylthio, alkoxyalkyl, acyl, benzyl, or alkoxycarbonyl.

L'invention concerne des composés de dihydro-oxadiazine insecticide ayant la formule (I) dans laquelle X représente O, N ou S; R représente un groupe phényle ou hétérocyclique C4-C5 substitué ou non substitué; R<2>, R<3>, R<4> et R<5> ont la définition suivante: a) R<2>, R<3> et R<4> représentent indépendamment, hydrogène, alkyle, alcoxy ou furanyle; et R<5> représente nitro, cyano, alkyle, dialkylamino, alkylthio, alcoxy, haloalcoxy, phénoxy, phénylthio ou alcoxycarbonyle, où R<3> et R<5> peuvent former ensemble un cycle; ou b) R<3>, R<4> et R<5> représentent hydrogène; et R<2> représente alkylthio, alkylsulfinyle, alkylsulfonyle, nitroalcoxy, hydroxy, dialcoxyphosphinyle, cyano, acyloxy, alcoxy, haloalcoxy, cycloalkyle ou alcényle; ou R<2> représente un phényle substitué ou non substitué, phénylthio, phénylsulfinyle, phénylsulfonyle, pyrazolyle, furanyle, thiényle, phénylalcoxy, ou benzoyloxy; et R<6> représente hydrogène, alkyle, alkylthio, alcoxyalkyle, acyle, benzyle ou alcoxycarbonyle.

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