Iodo compounds

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C - Chemistry, Metallurgy

07

C

C07C 67/05 (2006.01) C07C 69/63 (2006.01) C07C 69/86 (2006.01) C07C 201/12 (2006.01) C07C 205/43 (2006.01) C07C 253/30 (2006.01) C07C 255/55 (2006.01)

Patent

CA 2050902

11 ABSTRACT OF THE DISCLOSURE Diacetoxyarene compounds are obtained by reacting a perborate such as sodium perborate monohydrate or tetrahydrate and acetic acid with an iodoarene compound under mild conditions, such as 40 to 50°C. The iodoarene can be further substituted by a wide range of substituents, such as halo, nitro, alkyl, alkoxy or carboxylic acid, in any position around the nucleus, except that electron- withdrawing substituents occupy meta positions only. The invention process thus enables a wide range of substituted diacetoxyarene compounds to be produced using widely available and easily handled materials under mild operating conditions.

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