Iodonium salts as latent acid donors

Details Iodonium salts as latent acid donors Iodonium salts as latent acid donors

C - Chemistry, Metallurgy

07

C

C07C 25/18 (2006.01) C07C 309/19 (2006.01) C07C 309/30 (2006.01) C08F 2/46 (2006.01) C08J 3/20 (2006.01) C08J 3/24 (2006.01) C09D 7/12 (2006.01) G03F 7/004 (2006.01) G03F 7/031 (2006.01) G03F 7/038 (2006.01) C08G 59/68 (2006.01) C08G 65/10 (2006.01)

Patent

CA 2328819

Radiation-sensitive compositions comprising (a1) a cationically or acid-catalytically polymerisable or crosslinkable compound or (a2) a compound that increases its solubility in a developer under the action of acid; and (b) at least one diaryliodonium salt of formula I (see formula I) X is branched C3-C20alkyl or C3-C8cycloalkyl; X1 is hydrogen, linear C1-C20alkyl, branched C3-C20alkyl or C3-C8cycloalkyl; with the proviso that the sum of the carbon atoms in X and X1 is at least 4; Y is linear C1-C10alkyl, branched C3-C10alkyl or C3-C8cycloalkyl; A- is a non-nucleophilic anion, selected from the group (BF4)-, (SbF6)-, (PF6)- ,(B(C6F5))4- , C1-C20alkylsulfonate, C2-C20haloalkylsulfonate, unsubstituted C6- C10arylsulfonate, camphor- sulfonate, and C6-C10arylsulfonate substituted by halogen, NO2, C1-C12alkyl, C1-C12halo-alkyl, C1-C12alkoxy or by COOR1; and R1 is C1-C20alkyl, phenyl, benzyl; or phenyl mono- or poly-substituted by C1- C12alkyl, C1-C12alkoxy or by halogen; with the proviso that the two phenyl rings on the iodine atom are not identically substituted, have high sensitivity, high storage stability, good solubility and a low tendency to crystallise.

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