Ionic barrier

H - Electricity – 01 – M

Patent

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204/201, 319/49

H01M 2/14 (2006.01) H01M 2/16 (2006.01) H01M 6/24 (2006.01) H01M 10/04 (2006.01) H01M 10/36 (2006.01)

Patent

CA 1163318

ABSTRACT OF THE DISCLOSURE The invention features an electrochemical cell having two fluid-containing compartments separated by a nonselective microporous membrane. Select ions which would normally pass through the membrane under the influence of an ionic field, are prevented from passing through the membrane by a polyelectrolyte which has migrated through the compartment fluid to the membrane. The polyelectrolyte acts as an ionic barrier to the passage of select ions, thus effectively increasing the ion-selective capability of the membrane and, hence, the coulombic efficiency of the electrochemical cell.

361278

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