Ionic liquids

B - Operations – Transporting – 01 – J

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Details

B01J 31/00 (2006.01) C07C 2/26 (2006.01) C07C 2/54 (2006.01) C07C 2/58 (2006.01) C07C 2/66 (2006.01) C08F 4/00 (2006.01) C08F 10/00 (2006.01)

Patent

CA 2159479

This invention relates to an ionic liquid comprising a dialkyl substituted imidazolium halide wherein at least one of the said alkyl substituents has 6 or more carbon atoms, a method of preparation of such imidazolium halides, and the use thereof for hydrocarbon conversion reactions such as oligomerization or polymerization of olefins and for the alkylation of paraffins, isoparaffins or aromatics with olefins. Polymerization of C4 raffinates using these ionic liquids as catalysts enables a much higher percentage of n-butenes to be incorporated in the product polymer than would be possible in conventional cationic polymerization processes.

L'invention porte sur un liquide ionique comprenant un halogénure d'imidazolium à substitution dialkyle dans lequel au moins un desdits substituants alkyle comporte au moins 6 atomes de carbone, sur un procédé de préparation desdits halogénures d'imidazolium et sur leur emploi dans les réactions de conversion d'hydrocarbures telles que l'oligomérisation ou la polymérisation d'oléfines ou pour l'alkylation par les oléfines de paraffines, d'isoparaffines et de composés aromatiques. La polymérisation des produits de raffinage à C4 recourant à ces liquides ioniques comme catalyseurs permet d'atteindre un pourcentage beaucoup plus élevé de n-butènes s'incorporant au polymère résultant que lors des procédés classiques de polymérisation cationique.

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