Ionically polymer-bound transition metal complex for...

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252/52.D, 204/91

B01J 31/06 (2006.01) B01J 19/12 (2006.01) B01J 31/08 (2006.01) B01J 31/16 (2006.01) C07C 5/31 (2006.01) F24J 2/00 (2006.01)

Patent

CA 1251771

\ ABSTRACT OF THE DISCLOSURE Novel catalyst for the photochemical conversion and storage of radiant energy through the conversion of strained cyclic non-conjugated carbon containing compounds to their corresponding conjugated forms comprises ionically bonding a transition metal complex having a square planar geometry and multiple sites of coordination with an anion- exchange resin. A method is provided for the preparation of the novel catalyst and comprises forming an acid salt derivative of the transition metal complex and mixing it together with an anion-exchange resin. A process wherein the novel catalyst is added to a strained cyclic non-con- jugated carbon containing compound resulting in the release of heat energy through the conversion of the non-conjugated carbon containing compound to its conjugated form. A process and sealed container means wherein the non- conjugated carbon containing compound and the catalyst are in compartments and are separated until heat energy is required. The means of separation is then broken and the non-conjugated carbon containing compound is converted to the conjugated form with the release of heat energy. A process and apparatus wherein the conjugated carbon con- taining compound is exposed to radiant energy and is con- verted to the non-conjugated form. The non-conjugated form is then combined with the catalyst described hereinabove, converting the non-conjugated form to the conjugated form and resulting in the release of heat energy which is collected.

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