Iron oxide-based catalyst, its preparation and its use in a...

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B01J 23/83 (2006.01) B01J 23/85 (2006.01) B01J 23/887 (2006.01) B01J 37/08 (2006.01) C07C 5/333 (2006.01) C07C 15/067 (2006.01)

Patent

CA 2474607

A catalyst which is based upon an iron oxide and a compound of a lanthanide, of which iron oxide at least a portion is made by a process which involves heat decomposition of an iron halide, the lanthanide being in a quantity in the range of from 0.07 to 0.15 mole per mole iron oxide present in the catalyst, calculated as Fe2O3; a process for the preparation of the catalyst; a process for the dehydrogenation of an alkylaromatic compound which process involves contacting a feed containing the alkylaromatic compound with the catalyst; and a method of using an alkenylaromatic compound for making polymers or copolymers, in which method the alkenylaromatic compound has been prepared by the dehydrogenation process.

Catalyseur à base d'oxyde de fer et d'un composant de lanthanide, dont au moins une partie de l'oxyde de fer est obtenue au moyen d'un procédé consistant à effectuer la décomposition thermique d'un halogénure de fer, lanthanide étant présent en quantité de 0,07 à 0,15 molaire par mole d'oxyde de fer, calculé en tant que Fe¿2?O¿3?. Procédé servant à préparer ce catalyseur. Procédé servant à déshydrogéner un composé alkylaromatique et consistant à mettre en contact une charge contenant ce composé alkylaromatique avec le catalyseur. Procédé servant à mettre en application un composé alkénylaromatique afin de préparer des polymères ou des copolymères, ce composé alkénylaromatique ayant été préparé au moyen du procédé de déshydrogénation.

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