Irradiated multilayer film having seal layer containing...

B - Operations – Transporting – 32 – B

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B32B 27/32 (2006.01) B32B 1/02 (2006.01) B32B 27/00 (2006.01) B32B 27/08 (2006.01) B65D 65/40 (2006.01) C08L 23/08 (2006.01)

Patent

CA 2465205

An irradiated multilayer film has a first layer and a second layer. The first layer is an outer heat seal layer containing a blend of a highly branched homogenous polymer and a semicrystalline polymer. The highly branched homogenous polymer has at least 40 branches per 1000 methylene groups, an M~w/M~n less than than 3.0, and a density of less than 0.89 g/cc. The highly branched homogenous polymer is present in an amount of from about 5 to 50 weight percent, based on layer weight. The semicrystalline polyolefin has a density of at least 0.90 g/cc. The semicrystalline polyolefin is present in an amount of from about 50 to 95 weight percent, based on total layer weight. The second layer contains a thermoplastic polymer in a crosslinked polymer network. A process for making a packaging article includes coextruding the first and second layers, irradiating the resulting multilayer film, and thereafter heat sealing the first layer to itself or another component of the packaging article.

L'invention concerne un film multicouche irradi~ comprenant une premi­re et une deuxi­me couche. La premi­re couche constitue une couche d'~tanch~it~ ext~rieure contenant un m~lange constitu~ d'un polym­re homog­ne hautement ramifi~ et d'un polym­re semicristallin. Le polym­re homog­ne hautement ramifi~ comporte au moins 40 ramifications pour 1000 groupes m~thyl­ne, et il pr~sente un rapport M´w?/M´n? inf~rieur ~ 3,0 et une densit~ inf~rieure ~ 0,89 g/cc. Ce polym­re homog­ne hautement ramifi~ est pr~sent en quantit~ comprise entre environ 5 et 50 % en poids, en fonction du poids de la couche. La polyol~fine semicristalline est pr~sente en quantit~ comprise entre 50 et 95 % en poids, en fonction du poids total de la couche. La deuxi­me couche contient un polym­re thermoplastique dans un r~seau de polym­res r~ticul~s. L'invention concerne ~galement un proc~d~ de fabrication d'articles d'emballage consistant ~ co-extruder les premi­re et deuxi­me couches, ~ irradier le film multicouche r~sultant, puis ~ thermosceller la premi­re couche sur elle-mÚme ou sur un autre ~l~ment de l'article d'emballage.

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