Isolation of antisense oligonucleotides

C - Chemistry – Metallurgy – 12 – N

Patent

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C12N 15/10 (2006.01) B01D 15/08 (2006.01) B01D 15/38 (2006.01) B01J 45/00 (2006.01) C07H 1/06 (2006.01) C07H 1/08 (2006.01)

Patent

CA 2506196

The present invention relates to a method of isolating fully thioated single stranded antisense oligonucleotides from a biological solution, which method comprises the steps of contacting the biological solution with an immobilised metal ion adsorption chromatography (IMAC) resin to adsorb the antisense oligonucleotides to said resin and subsequently contacting the resin with an eluent under conditions that provide desorption of the antisense oligonucleotides from said resin, wherein the fully thioated antisense oligonucleotides are separated from incorrectly thioated antisense oligonucleotides in said solution. The invention also relates to the use of an immobilised metal ion adsorption chromatography (IMAC) resin for isolation of fully thioated single stranded antisense oligonucleotides from a biological solution.

La présente invention concerne un procédé pour isoler des oligonucléotides antisens à simple brin complètement thioatés d'une solution biologique. Ce procédé consiste à mettre en contact la solution biologique avec une résine de chromatographie par adsorption d'ions métalliques immobilisés (IMAC), afin d'adsorber les oligonucléotides antisens sur ladite résine, puis à mettre en contact la résine avec un éluant, dans des conditions qui permettent la désorption des oligonucléotides antisens de la résine, les oligonucléotides antisens complètement thioatés étant séparés des oligonucléotides antisens incorrectement thioatés dans ladite solution. La présente invention concerne également l'utilisation d'une résine de chromatographie par adsorption d'ions métalliques immobilisés (IMAC) afin d'isoler des oligonucléotides antisens à simple brin complètement thioatés d'une solution biologique.

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