Isomer enrichment process for cyclopropanecarboxylates

Details Isomer enrichment process for cyclopropanecarboxylates Isomer enrichment process for cyclopropanecarboxylates

C - Chemistry, Metallurgy

07

C

260/518, 260/479

C07C 61/16 (2006.01) C07C 51/487 (2006.01) C07C 69/743 (2006.01)

Patent

CA 1192218

ABSTRACT A method of partially resolving the cis and trans isomers of a cyclopropane carboxylate by a controlled partial hydrolysis. The cis/trans distribution in the hydrolyzed product differs from that in the starting material. The cyclopropane carboxylates are known intermediates for the natural and synthethic pyrethroids, some of which exhibit a difference in pesticidal activity depending on whether the cis or trans isomers are applied.

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