Isopropyl t-butyl ether (iptbe) generation from grude acetone

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 43/04 (2006.01) C07C 29/145 (2006.01) C07C 41/01 (2006.01) C07C 41/09 (2006.01)

Patent

CA 2139295

Disclosed is a two-step process for the generation of isopropyl t-butyl ether from a crude by-product acetone stream which comprises: a) Hydrogenating said crude acetone over a bulk metal, nickel-rich catalyst to give an isopropanol-rich effluent; b) subjecting said isopropanol-rich intermediate to etherification conditions in the presence of a strong acid catalyst selected from: (1) a cationic resin; (2) a .beta.-zeolite; (3) dealuminized y-zeolites; and (4) metal-modified .beta.-zeolites.

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