Ketones from olefins by oxidation process

Details Ketones from olefins by oxidation process Ketones from olefins by oxidation process

C - Chemistry, Metallurgy

07

C

260/577, 260/582

C07C 45/00 (2006.01) C07C 45/34 (2006.01) C07C 49/76 (2006.01)

Patent

CA 1097686

Abstract of the Disclosure Olefins are oxidized to carbonyl compounds, for example, 1-hexene to 2-hexanone, with a Pd/Cu/alkali metal or alkaline earth metal chloride catalyst and a suitable surfactant in a diluent system comprising at least two liquid phases, wherein at least one liquid phase is an aqueous phase, in the presence of free oxygen. The addition of the surfactant to the system provides an improvement in olefin conversion and selectively to the corresponding carbonyl compound. Suitable surfactants include, for example, quarternary ammonium halide compounds.

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